A Zn(Ⅱ) Coordination Polymer with 4-Connected bbf Topology: Synthesis, Crystal Structure and Luminescent Property

被引：1
|
作者：
张鑫 [1 ,2 ]
覃业燕 [1 ]
孙明玲 [1 ]
姚元根 [1 ]
机构：
[1] Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
[2] University of Chinese Academy of Sciences
来源：
结构化学 | 2016年 / 35卷 / 07期
关键词：
Zn(Ⅱ) compound; topology; 3D framework; luminescence;
D O I：
暂无
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
A new Zn（Ⅱ） compound, namely {Zn（BTA）(pdc);};（1, HBTA = 1,2,3-benzotriazole, H;pdc = terephthalic acid）, has been hydrothermally synthesized and characterized by elemental analysis, infrared analysis, powder X-ray diffraction analysis and single-crystal X-ray structural analysis. The crystal structure is of monoclinic system, space group P21/c with a = 10.751（3）, b = 9.792（3）, c = 9.292（3） ?, β = 95.391（4）°, V = 973.9（5） ?3, C10H6N3O2 Zn, Mr = 265.57, Z = 4, Dc = 1.811 g/cm3, F（000） = 532, μ = 2.506 mm-1, R = 0.0221 and w R = 0.0605 for 2075 observed reflections(I > 2s（I）). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional（3D） framework with 4-connected bbf topology. Moreover, the thermogravimetric（TG） analysis and photoluminescent property of 1 were also discussed.
引用
收藏
页码：1145 / 1150
页数：6
相关论文
共 50 条
  • [31] Synthesis, structure, photoluminescence and theoretical calculation on a novel Zn(II) coordination polymer with (4,8)-connected topology
    Zhang, Xin
    Sun, Ming-Ling
    Huang, Yuan-Yuan
    Yao, Yuan-Gen
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 37 : 155 - 157
  • [32] A copper sulfoisophthalate dipyridylpropane coordination polymer with a new, simple 4,4,4-connected trinodal topology
    Gandolfo, Chaun M.
    Allen, Corinne
    LaDuca, Robert L.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 37 : 71 - 76
  • [33] A Unique (3,3,4)-Connected CdII Coordination Polymer with Dicarboxylate and Imidazole-Containing Coligands: Synthesis, Crystal Structure, and Luminescent Property
    Jia, Huali
    Wang, Chunjie
    Guo, Feng
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (12-13): : 2508 - 2511
  • [34] Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a New Cd(II) Coordination Polymer with Four-fold Interpenetrated dia Topology
    Kong Chun-Yan
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (02) : 267 - 271
  • [35] A Coordination Polymer With a (3,4)-Connected (62.8)2(62.84) 3D Network: Synthesis, Crystal Structure and Luminescent Properties
    Liu, Guang-Xiang
    Guo, Wei
    Nishihara, Sadafumi
    Ren, Xiao-Ming
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (09) : 1222 - 1226
  • [36] A Cadmium Coordination Polymer with a (4,6)-Connected 3D Network: Synthesis, Crystal Structure, and Luminescent Properties
    Xu, Yun
    Che, Yun-Xia
    Zheng, Ji-Min
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (3-4): : 698 - 701
  • [37] Synthesis, Crystal Structure and Luminescence of a Cadmium(Ⅱ) Coordination Polymer with 3,6-Connected rtl Topology
    XUE Li-Ping
    SHAN Li-Li
    FENG Wen-Jing
    结构化学, 2016, 35 (02) : 293 - 297
  • [38] Synthesis, Crystal Structure, and Luminescent Property of a Cd(II) Coordination Polymer with a N-Nicotinoylglycine Ligand
    Tai, Xi-Shi
    Wang, Xin
    Li, Peng-Fei
    CRYSTALS, 2017, 7 (02):
  • [39] Synthesis, crystal structure, and topology of a polycatenated bismuth coordination polymer
    Grape, Erik Svensson
    Ruser, Niklas
    Rooth, Victoria
    Cheung, Ocean
    Inge, A. Ken
    Stock, Norbert
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2022, 77 (4-5): : 231 - 236
  • [40] Synthesis, structure and luminescent property of a pillared-layer coordination polymer [Pb(BPDC)] (BPDC=4,4′-biphenyldicarboxylate)
    Hu, Ranran
    Cai, Hu
    Luo, Junhua
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (02) : 433 - 436
12345