A Zn(Ⅱ) Coordination Polymer with 4-Connected bbf Topology: Synthesis, Crystal Structure and Luminescent Property

被引：1
|
作者：
张鑫 [1 ,2 ]
覃业燕 [1 ]
孙明玲 [1 ]
姚元根 [1 ]
机构：
[1] Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
[2] University of Chinese Academy of Sciences
来源：
结构化学 | 2016年 / 35卷 / 07期
关键词：
Zn(Ⅱ) compound; topology; 3D framework; luminescence;
D O I：
暂无
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
摘要：
A new Zn（Ⅱ） compound, namely {Zn（BTA）(pdc);};（1, HBTA = 1,2,3-benzotriazole, H;pdc = terephthalic acid）, has been hydrothermally synthesized and characterized by elemental analysis, infrared analysis, powder X-ray diffraction analysis and single-crystal X-ray structural analysis. The crystal structure is of monoclinic system, space group P21/c with a = 10.751（3）, b = 9.792（3）, c = 9.292（3） ?, β = 95.391（4）°, V = 973.9（5） ?3, C10H6N3O2 Zn, Mr = 265.57, Z = 4, Dc = 1.811 g/cm3, F（000） = 532, μ = 2.506 mm-1, R = 0.0221 and w R = 0.0605 for 2075 observed reflections(I > 2s（I）). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional（3D） framework with 4-connected bbf topology. Moreover, the thermogravimetric（TG） analysis and photoluminescent property of 1 were also discussed.
引用
收藏
页码：1145 / 1150
页数：6
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