A soluble polymer-supported NADH model:Synthesis and application

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作者
MEI LianRuiZHU XiaoQing CHENG JinPei Department of Chemistry and the State Key Laboratory of ElementoOrganic ChemistryNankai UniversityTianjin China [300071 ]
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O631 [高分子物理和高分子物理化学];
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摘要
A polyethylene glycol (PEG)-supported NADH model as a novel organic reductant was designed and synthesized. The reductions of various α,β-unsaturated ketones by the PEG-supported NADH model were examined,and the results showed that the reductions completely and quickly proceed with no catalyst at ambient temperature. The main advantages of this liquid-like PEG-supported NADH model are easy workup,and an optimal potential for recycling use and solvent-free for use in reactions.
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页码:2824 / 2828
页数:5
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  • [1] Telechelic polymers with azido functions as reagents for 1;3-dipolar cycloaddition reactions.[J].M. Neumann;K.E. Geckeler.Reactive and Functional Polymers.1997, 2