Photodegradation of N-nitrosodiethylamine in water with UV irradiation

被引：0

作者：

XU BingBingCHEN ZhongLinQI Fei YANG Lei State Key Laboratory of Urban Water Resource and EnvironmentSchool of Municipal Environmental EngineeringHarbin Institute of TechnologyHarbin China ^{[150090
]}

机构：

来源：

ChineseScienceBulletin | 2008年 / 21期

关键词：

N-nitrosodiethylamine; ultraviolet irradiation; diethylamine; ethylamine;

D O I：

暂无

中图分类号：

O623.737 [胺类的硝基衍生物];

学科分类号：

070303 ; 081704 ;

摘要：

The direct photolysis of N-nitrosodiethylamine(NDEA) in water with ultraviolet(UV) irradiation was investigated.Results showed that NDEA could be completely degraded under the direct UV irradiation.The effects of the experimental conditions,including the initial concentration of NDEA,humic acid and solution pH,were studied.The degradation products of NDEA were identified and quantified with gas chromatography-mass spectrometry(GC-MS) and high performance liquid chromatography(HPLC).It was confirmed that methylamine(MA),dimethylamine(DMA),ethylamine(EA),diethylamine(DEA),NO2-and NO3-were the main degradation products.The photolysis degradation mechanism of NDEA was also discussed.As a result of N-N bond fission,NDEA was degraded by direct UV irradiation.

引用

页码：3395 / 3401

页数：7

共 9 条

[1] Evaluation of nitroreductase and acetyltransferase participation in N-nitrosodiethylamine genotoxicity [J].

Aiub, CAF ;

Mazzei, JL ;

Pinto, LFR ;

Felzenszwalb, I .

CHEMICO-BIOLOGICAL INTERACTIONS, 2006, 161 (02) :146-154

[2]

Protective role of Vitamin E pre-treatment on N -nitrosodiethylamine induced oxidative stress in rat liver[J] . Anil K Bansal,Manju Bansal,Giridhar Soni,Deepak Bhatnagar.Chemico-Biological Interactions . 2005 (2)

[3]

N -Nitrosodiethylamine mutagenicity at low concentrations[J] . Claudia Alessandra Fortes Aiub,Luis Felipe Ribeiro Pinto,Israel Felzenszwalb.Toxicology Letters . 2003 (1)

[4] Spectroscopic characterization of the structural and functional properties of natural organic matter fractions [J].

Chen, J ;

Gu, BH ;

LeBoeuf, EJ ;

Pan, HJ ;

Dai, S .

CHEMOSPHERE, 2002, 48 (01) :59-68

[5]

Formation of N -nitrosodimethylamine (NDMA) from reaction of monochloramine: a new disinfection by-product[J] . Junghoon Choi,Richard L. Valentine.Water Research . 2002 (4)

[6] Excretion of volatile nitrosamines in a rural population in relation to food and drinking water consumption [J].

Levallois, P ;

Ayotte, P ;

Van Maanen, JMS ;

Desrosiers, T ;

Gingras, S ;

Dallinga, JW ;

Vermeer, ITM ;

Zee, J ;

Poirier, G .

FOOD AND CHEMICAL TOXICOLOGY, 2000, 38 (11) :1013-1019

[7]

Analysis of primary and secondary aliphatic amines in waste water and surface water by gas chromatography-mass spectrometry after derivatization with 2,4-dinitrofluorobenzene or benzenesulfonyl chloride[J] . Frank Sacher,Steffen Lenz,Heinz-Jürgen Brauch.Journal of Chromatography A . 1997 (1)

[8]

N-Nitrosodiethylamine mechanistic data and risk assessment: Bioactivation, DNA-adduct formation, mutagenicity, and tumor initiation[J] . Lynne Verna,John Whysner,Gary M. Williams.Pharmacology and Therapeutics . 1996 (1)

[9]

Nitrate-induced photolysis in natural waters: controls on concentrations of hydroxyl radical photo-intermediates by natural scavenging agents .2 Brezonik,P. L.,Brekken,J. F. Environ Sci Technol . 1998

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