Metal-Oxo Cluster Catalysts for Photocatalytic Water Splitting and Carbon Dioxide Reduction

被引：0

作者：

Qing Lan ^{[1
]}

Sujuan Jin ^{[1
]}

Bohan Yang ^{[1
]}

Qiang Zhao ^{[1
]}

Chaolei Si ^{[1
]}

Haiquan Xie ^{[1
]}

Zhiming Zhang ^{[2
]}

机构：

[1] Engineering Technology Research Center of Henan Province for Solar Catalysis, College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University

[2] Institute of New Energy Materials and Low Carbon Technology, Tianjin University of

来源：

Transactions of Tianjin University | 2022年 / 03期

关键词：

D O I：

暂无

中图分类号：

O643.36 [催化剂];

学科分类号：

摘要：

Photocatalytic water splitting and carbon dioxide photoreduction are considered effective strategies for alleviating the energy crisis and environmental pollution. Polynuclear metal-oxo clusters possess excellent electron storage/release ability and unique catalytic properties via intermetallic synergy, which enables them with great potential in environmentally friendly photosynthesis. Importantly, metal-oxo clusters with precise structure can not only act as high-efficiency catalysts but also provide well-defined structural models for exploring structure–activity relationships. In this review, we systematically summarize recent progress in the catalytic application of polynuclear metal-oxo clusters, including polyoxometalate clusters, lowcost transition metal clusters, and metal-oxo-cluster-based metal–organic frameworks for water splitting and CO2 reduction. Furthermore, we discuss the challenges and solutions to the problems of polynuclear metal-oxo clusters in photocatalysis.

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页码：214 / 225

页数：12

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