Au–Agalloynanoparticleswithtunablecavityforplasmon-enhancedphotocatalyticH2evolution

被引：8

作者：

Xuanyu Yue ^{[1
,2
]}

Juan Hou ^{[1
,3
]}

Haifeng Zhao ^{[3
]}

Pengcheng Wu ^{[2
]}

Yali Guo ^{[1
,2
]}

Qin Shi ^{[1
]}

Long Chen ^{[2
]}

Shanglong Peng ^{[1
]}

Zhiyong Liu ^{[2
]}

Guozhong Cao ^{[4
]}

机构：

[1] College of Science/Key Laboratory of Ecophysics and Department of Physics, Shihezi University

[2] School of Chemistry and Chemical Engineering/Key Laboratory for Green Process of Chemical Engineering of Xinjiang Bingtuan, Shihezi University

[3] Center for Applied Chemistry/School of Materials and Energy, University of Electronic Science and Technology of China

[4] Department of Materials and Engineering, University of Washington

来源：

Journal of Energy Chemistry | 2020年 / 49卷 / 10期

关键词：

D O I：

暂无

中图分类号：

TB383.1 []; O643.36 [催化剂]; O644.1 [光化学];

学科分类号：

070205 ; 080501 ; 1406 ; 081705 ; 070304 ; 081704 ;

摘要：

Au–Ag alloy nanoparticles with different cavity sizes have great potential for improving photocatalytic performance due to their tunable plasmon effect. In this study, galvanic replacement was combined with co-reduction with the reaction kinetics processes regulated to rapidly synthesize Au–Ag hollow alloy nanoparticles with tunable cavity sizes. The position of the localized surface plasmon resonance（LSPR）peak could be effectively adjusted between 490 nm and 713 nm by decreasing the cavity size of the Au–Ag hollow nanoparticles from 35 nm to 20 nm. The plasmon-enhanced photocatalytic H2 evolution of alloy nanoparticles with different cavity sizes was investigated. Compared with pure P25（TiO2）, intact and thin-shelled Au–Ag hollow nanoparticles（HNPs）-supported photocatalyst exhibited an increase in the photocatalytic H2 evolution rate from 0.48 μmol h-1 to 4 μmol h-1 under full-spectrum irradiation. This improved photocatalytic performance was likely due to the plasmon-induced electromagnetic field effect,which caused strong photogenerated charge separation, rather than the generation of hot electrons.

引用

页码：1 / 7

页数：7

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