EVALUATION OF SPECIFIC INTERACTIONS OF SOLID-SURFACES BY INVERSE GAS-CHROMATOGRAPHY - A NEW APPROACH BASED ON POLARIZABILITY OF THE PROBES

被引：186

作者：

DONNET, JB ^{[1
]}

PARK, SJ ^{[1
]}

BALARD, H ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM,CHIM PHYS LAB,F-68093 MULHOUSE,FRANCE

来源：

CHROMATOGRAPHIA | 1991年 / 31卷 / 9-10期

关键词：

INVERSE GAS CHROMATOGRAPHY; DEFORMATION POLARIZABILITY; LONDON DISPERSIVE FORCES AND SPECIFIC INTERACTIONS; NATURAL GRAPHITE;

D O I：

10.1007/BF02262385

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A method is presented for the determination of London dispersive forces and specific interactions between adsorbate and adsorbent, taking into account the deformation polarizability in inverse gas chromatography (IGC) at infinite dilution. Previous methods for the interpretation of IGC experimental results have frequently revealed their inadequacies and limits in the case of solids such as carbon blacks, graphite powders and carbon fibres, or led to rough estimations when based on molar deformation polarization only.

引用

页码：434 / 440

页数：7

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