STEREOCHEMICAL STUDIES ON THE BIOSYNTHESIS OF VIRIDICATUMTOXIN - EVIDENCE FOR A 1,3-HYDRIDE SHIFT IN THE FORMATION OF THE SPIROBICYCLIC RING-SYSTEM

被引：9
作者：
HORAK, RM [1 ]
MAHARAJ, VJ [1 ]
MARAIS, SF [1 ]
VAN HEERDEN, FR [1 ]
VLEGGAAR, R [1 ]
机构：
[1] CSIR, DIV FOOD SCI & TECHNOL, POB 395, PRETORIA 0001, SOUTH AFRICA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1988年 / 23期
关键词：
D O I：
10.1039/c39880001562
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：1562 / 1564
页数：3
相关论文
共 15 条
[1]   THE USE OF H-2 NMR-SPECTROSCOPY AND BETA-ISOTOPIC SHIFTS IN THE C-13 NMR-SPECTRUM TO MEASURE DEUTERIUM RETENTION IN THE BIOSYNTHESIS OF THE POLYKETIDE 6-METHYLSALICYLIC ACID [J].
ABELL, C ;
STAUNTON, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (16) :856-858
[2]   AN IMPROVED METHOD FOR HETERONUCLEAR CHEMICAL-SHIFT CORRELATION BY TWO-DIMENSIONAL NMR [J].
BAX, A ;
MORRIS, GA .
JOURNAL OF MAGNETIC RESONANCE, 1981, 42 (03) :501-505
[3]   CORRELATION OF PROTON AND C-13 NMR-SPECTRA BY HETERONUCLEAR 2-DIMENSIONAL SPECTROSCOPY [J].
BODENHAUSEN, G ;
FREEMAN, R .
JOURNAL OF MAGNETIC RESONANCE, 1977, 28 (03) :471-476
[4]   BIOSYNTHESIS OF VIRIDICATUMTOXIN, A MYCO-TOXIN FROM PENICILLIUM-EXPANSUM [J].
DE JESUS, AE ;
HULL, WE ;
STEYN, PS ;
VAN HEERDEN, FR ;
VLEGGAAR, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (16) :902-904
[5]   TREMORGENIC MYCO-TOXINS FROM PENICILLIUM-CRUSTOSUM - BIOSYNTHESIS OF PENITREM-A [J].
DE JESUS, AE ;
GORSTALLMAN, CP ;
STEYN, PS ;
VAN HEERDEN, FR ;
VLEGGAAR, R ;
WESSELS, PL ;
HULL, WE .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1983, (08) :1863-1868
[6]  
Derome A. E., 1987, MODERN NMR TECHNIQUE
[7]   BIOSYNTHESIS OF VERRUCULOGEN, A TREMORGENIC METABOLITE OF PENICILLIUM-VERRUCULOSUM - STEREOCHEMICAL COURSE OF PEROXIDE RING FORMATION [J].
HORAK, RM ;
VLEGGAAR, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (20) :1568-1570
[8]   VIRIDICATUMTOXIN, A NEW MYCOTOXIN FROM PENICILLIUM-VIRIDICATUM WESTLING [J].
HUTCHISO.RD ;
STEYN, PS ;
VANRENSB.SJ .
TOXICOLOGY AND APPLIED PHARMACOLOGY, 1973, 24 (03) :507-509
[9]   X-RAY STRUCTURE OF VIRIDICATUMTOXIN - NEW CLASS OF MYCOTOXIN FROM PENICILLIUM-VIRIDICATUM WESTLING [J].
KABUTO, C ;
SILVERTON, JV ;
AKIYAMA, T ;
SANKAWA, U ;
HUTCHISON, RD ;
STEYN, PS ;
VLEGGAAR, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (18) :728-729
[10]   THE STRUCTURE AND ABSOLUTE-CONFIGURATION OF VIRIDICATUMTOXIN - 2'S-(2'-ALPHA,7'A-BETA,11'A-BETA,12'-BETA)-7',7'A,8',11',11'A,12'-HEXAHYDRO-5',6',7'A,10',11'A,12'-HEXAHYDROXY-3'-METHOXY-2,6,6-TRIMETHYL-7',8'-DIOXOSPIRO[2-CYCLOHEXENE-1,2'(1'H)-CYCLOPENTA[DE]NAPHTHACENE]-9'-CARBOXAMIDE METHANOLATE [J].
SILVERTON, JV ;
KABUTO, C ;
AKIYAMA, T .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (DEC) :3032-3037
12