A new method of predicting adsorption equilibria for multicomponent liquid solutions on solids has been developed which combines the thermodynamic and kinetic treatments of liquid adsorption. Multicomponent equilibria can be predicted using parameters obtained from binary adsorption data. The method requires the adsorbent capacities, the bulk and surface phase activity coefficients, and the binary adsorption equilibrium constants. The calculation procedure is simpler than other available methods. Predictions are made for the mixture of benzene, ethyl acetate, and cyclohexane on activated carbon at 303 K. The predictions are in quantitative agreement with published experimental data for this system.
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Feo, Maria Luisa
Frattoni, Massimiliano
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Frattoni, Massimiliano
Paoloacci, Ester
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Sapienza Univ Rome, Dept Chem, Piazzale Aldo Moro 5, I-00185 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Paoloacci, Ester
Masiello, Maria
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Sapienza Univ Rome, Dept Chem, Piazzale Aldo Moro 5, I-00185 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Masiello, Maria
Esposito, Giulio
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Esposito, Giulio
Gonzalez-Olmos, Rafael
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Univ Ramon Llull, IQS Sch Engn, Via Augusta 390, Barcelona 08017, SpainNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Gonzalez-Olmos, Rafael
Tempesta, Emanuela
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Natl Res Council Italy CNR IIA, Inst Environm Geol & Geoengn, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Tempesta, Emanuela
Trapasso, Francesca
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Natl Res Council Italy CNR IIA, Inst Environm Geol & Geoengn, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Trapasso, Francesca
Zampetti, Emiliano
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Zampetti, Emiliano
Torre, Marco
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Torre, Marco
Guerriero, Ettore
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy
Guerriero, Ettore
Paolini, Valerio
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Natl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, ItalyNatl Res Council Italy CNR IIA, Inst Atmospher Pollut Res, Via Salaria Km 29-300, I-00015 Rome, Italy