Stress Relaxation of Poly(methyl acrylate)-Poly( acrylonitrile) Copolymers

被引:0
|
作者
Kim, Nam Jeong [1 ]
机构
[1] Sahmyook Univ, Dept Chem, Kongrung 2 Dong 26-21, Seoul 139742, South Korea
来源
ELASTOMERS AND COMPOSITES | 2012年 / 47卷 / 03期
关键词
poly(methyl acrylate)-poly(acrylonitrile) copolymers; stress relaxation; Eyring-Halsey non-Newtonian model; tensile tester; rheological parameters;
D O I
10.7473/EC.2012.47.3.223
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The rheological parameters of poly(methyl acrylate)-poly(acrylonitrile) copolymers were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The experimentals of stress relaxation were carried out using the tensile tester with the solvent chamber. The determination of rheological parameters was performed from computer calculation. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusions and viscosities and activation energies of flow segments.
引用
收藏
页码:223 / 230
页数:8
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