ON THE ASYMMETRIC RH(I) CATALYZED [4+2] CYCLOISOMERIZATION REACTION - ELECTRONIC AND TORSIONAL LIGAND CONTROL OF ABSOLUTE STEREOSELECTION

被引：117

作者：

MCKINSTRY, L ^{[1
]}

LIVINGHOUSE, T ^{[1
]}

机构：

[1] MONTANA STATE UNIV,DEPT CHEM & BIOCHEM,BOZEMAN,MT 59717

来源：

TETRAHEDRON | 1994年 / 50卷 / 21期

关键词：

D O I：

10.1016/S0040-4020(01)80636-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of bisphosphine ligands related to DIOP as chiral modifiers in the Rh(I) catalyzed [4+2] cycloisomerization reaction results in moderate to good levels of enantioselection. The mode of absolute stereoinduction is subject to electronic and torsional modification of the chelating ligand.

引用

页码：6145 / 6154

页数：10