COMPARATIVE KINETIC ANALYSES FOR EPOXY-RESINS CURED WITH IMIDAZOLE METAL-COMPLEXES

被引：31

作者：

BUIST, GJ ^{[1
]}

HAMERTON, I ^{[1
]}

HOWLIN, BJ ^{[1
]}

JONES, JR ^{[1
]}

LIU, SY ^{[1
]}

BARTON, JM ^{[1
]}

机构：

[1] DEF RES AGCY,CTR STRUCT MAT,FARNBOROUGH GU14 6TD,HANTS,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1994年 / 4卷 / 12期

关键词：

D O I：

10.1039/jm9940401793

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Proton nuclear magnetic resonance (H-1 NMR) spectroscopy experiments were carried out for a commercial epoxy resin system in [H-2(6)]DMSO solution and in bulk. Good agreement was obtained between the secondary rate constants found for the epoxide polyetherification reaction when monitored by Fourier-transform infrared (FTIR) or H-1 NMR spectroscopy in the bulk over the range of temperatures studied. This highlights the usefulness of the high temperature bulk NMR technique in kinetic studies of polymerization.

引用

页码：1793 / 1797

页数：5

共 12 条

[1] ASHCROFT WR, 1993, CHEM TECHNOLOGY EPOX, P58
[2] HIGH-TEMPERATURE H-1-NMR STUDIES OF EPOXY CURE - A NEGLECTED TECHNIQUE
BARTON, JM
BUIST, GJ
HAMERTON, I
HOWLIN, BJ
JONES, JR
LIU, SY
[J]. POLYMER BULLETIN, 1994, 33 (02) : 215 - 219
[3] THE DEVELOPMENT OF CONTROLLABLE METAL-CHELATE CURING AGENTS WITH IMPROVED STORAGE STABILITY
BARTON, JM
HAMERTON, I
HOWLIN, BJ
JONES, JR
LIU, SY
[J]. POLYMER BULLETIN, 1994, 33 (03) : 347 - 353
[4] PREPARATION AND CHARACTERIZATION OF IMIDAZOLE-METAL COMPLEXES AND EVALUATION OF CURED EPOXY NETWORKS
BARTON, JM
BUIST, GJ
HAMERTON, I
HOWLIN, BJ
JONES, JR
LIU, SU
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (03) : 379 - 384
[5] BARTON JM, 1975, MAKROMOL CHEM, V176, P919
[6] BARTON JM, 1984, Patent No. 2135316
[7] BOUILLON N, 1990, MAKROMOL CHEM, V191, P1417
[8] BUIST GJ, 1988, POLYM COMMUN, V29, P5
[9] THERMAL-PROPERTIES OF EPOXY-RESIN CURED WITH IMIDAZOLE
ITO, M
HATA, H
KAMAGATA, K
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1987, 33 (05) : 1843 - 1848
[10] JACKSON RJ, 1987, SAMPE J, V23, P16

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