STABLE CARBONIUM IONS .55. PROTONATED ALICYCLIC KETONES

被引：61
作者：
OLAH, GA
CALIN, M
机构：
[1] Department of Chemistry, Case Western Reserve University, Cleveland
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 04期
关键词：
D O I：
10.1021/ja01006a017
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The pmr parameters of O-protonated alicyclic ketones in SbF5-FSO3H-SO2 and FSO3H-SO2 solutions at –60° have been determined. Analysis of the pmr data leads to the conclusion that the structure of protonated ketones is best represented by the oxonium ion resonance form, with little contribution from the hydroxycarbonium ion form. © 1968, American Chemical Society. All rights reserved.
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页码：938 / &
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