STOPPED-FLOW X-RAY ABSORPTION SPECTROSCOPY IN DISPERSIVE MODE

被引：11

作者：

Saigo, S. ^{[1
]}

Oyanagi, H. ^{[2
]}

Matsushita, T. ^{[3
]}

Hashimoto, H. ^{[4
]}

Yoshida, N. ^{[5
]}

Fujimoto, M. ^{[5
]}

Nagamura, T. ^{[6
]}

机构：

[1] Jichi Med Sch, Dept Phys, Minami Kawachi, Tochigi 32904, Japan

[2] Electrotech Lab, Sakura, Ibaraki 305, Japan

[3] Natl Lab High Energy Phys, Photon Factory, Oho, Ibaraki 305, Japan

[4] Toray Res Ctr, Otsu, Shiga 520, Japan

[5] Hokkaido Univ, Fac Sci, Dept Chem 2, Sapporo, Hokkaido 060, Japan

[6] Unisoku Inc, Hirakata, Osaka 57301, Japan

来源：

JOURNAL DE PHYSIQUE | 1986年 / 47卷 / C-8期

关键词：

D O I：

10.1051/jphyscol:19868104

中图分类号：

学科分类号：

摘要：

A new stopped-flow device particularly suitable for X-ray absorption spectroscopy in dispersive mode has been built. Time-resolved measurements of X-ray absorption spectra have been made for reactions in mixed solutions of (i) iron(III) nitrate and catechol and (ii) iron(III) nitrate and sodium thiosulfate with time resolutions of similar to 5 ms to a few seconds. Two-step variation of the spectra was observed for the former reaction, while one-step variation for the latter.

引用

页码：42 / 48

页数：7

共 11 条

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