ELECTROREDUCTION OF REFRACTORY-METAL COMPLEXES IN SALT MELTS - SPECIFIC FEATURES AND RELATIONSHIPS

被引：0
|
作者：
KUZNETSOV, SA
机构：
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 1993年 / 29卷 / 11期
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D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electroreduction of refractory-metal (Hf, Nb, Cr, Re, Ir) complexes in halide and oxyhalide melts is examined. The effects of the anionic and cationic composition of the melt, temperature, concentration, and rate of polarization on the steps and mechanism involved in electroreduction are discussed. The kinetic parameters, such as diffusion and transfer coefficients, and heterogeneous charge transfer rate constants, are defined for the discharge of refractory-metal complexes.
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页码：1154 / 1160
页数：7
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