NMR-STUDY OF THE PROTONATION OF DOMOIC ACID

被引：34
|
作者：
WALTER, JA [1 ]
LEEK, DM [1 ]
FALK, M [1 ]
机构：
[1] NATL RES COUNCIL CANADA,INST MARINE BIOSCI,1411 OXFORD ST,HALIFAX B3H 3Z1,NS,CANADA
来源：
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1992年 / 70卷 / 04期
关键词：
D O I：
10.1139/v92-151
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The H-1 and C-13 NMR spectra of the amnesic shellfish poison, domoic acid, in H2O and D2O solutions have been studied as a function of pH or pD. The results yielded the NMR spectral parameters for each of the five protonation stages of domoic acid, provided accurate pK(a) values, and enabled each pK(a) be associated with a particular protonation site.
引用
收藏
页码：1156 / 1161
页数：6
相关论文
共 50 条
  • [1] PROTONATION TENDENCIES OF AZAPARACYCLOPHANES - A THERMODYNAMIC AND NMR-STUDY
    BIANCHI, A
    ESCUDER, B
    GARCIAESPANA, E
    LUIS, SV
    MARCELINO, V
    MIRAVET, JF
    RAMIREZ, JA
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (06): : 1253 - 1259
  • [2] MULTINUCLEAR NMR-STUDY OF PROTONATION IN SOME INDOLIZINE SYSTEMS
    WIENCH, JW
    STEFANIAK, L
    WEBB, GA
    MAGNETIC RESONANCE IN CHEMISTRY, 1994, 32 (06) : 373 - 375
  • [3] A O-17 NMR-STUDY OF THE PROTONATION OF UREA
    VALENTINE, B
    STAMOUR, TE
    FIAT, D
    ORGANIC MAGNETIC RESONANCE, 1984, 22 (11): : 697 - 700
  • [4] NMR-STUDY OF THE CONFIGURATION AND PROTONATION EQUILIBRIA OF A PYRAZOLOTRIAZOLE AZOMETHINE DYE
    DOUGLAS, P
    COUTURE, C
    CLARKE, D
    REED, D
    SADLER, IH
    WEAR, T
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (06): : 1295 - 1298
  • [5] A C-13 NMR-STUDY OF THE PROTONATION OF 3,5-DIHYDROXYBENZOIC ACID IN AQUEOUS SULFURIC-ACID
    HALDNA, U
    LINASK, K
    KUURA, H
    KUDRYASHOVA, M
    MENDELEEV COMMUNICATIONS, 1994, (01) : 22 - 23
  • [6] C-13 NMR-STUDY OFBLEOMYCIN-A2 PROTONATION
    MOOBERRY, ES
    DALLAS, JL
    SAKAI, TT
    GLICKSON, JD
    INTERNATIONAL JOURNAL OF PEPTIDE AND PROTEIN RESEARCH, 1980, 15 (04): : 365 - 376
  • [7] NMR-STUDY OF SOLID HIPPURIC ACID
    TANDON, P
    BANERJEE, AK
    GUPTA, RC
    INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 1974, 12 (07) : 533 - 534
  • [8] OKADAIC ACID - A PROTON AND CARBON NMR-STUDY
    NORTE, M
    GONZALEZ, R
    FERNANDEZ, JJ
    RICO, M
    TETRAHEDRON, 1991, 47 (35) : 7437 - 7446
  • [9] NMR STUDY OF PROTONATION OF PHOSPHINE HYPOPHOSPHOROUS ACID AND ORTHOPHOSPHOROUS ACID
    SHELDRIC.GM
    TRANSACTIONS OF THE FARADAY SOCIETY, 1967, 63 (533P): : 1077 - &
  • [10] AN NMR-STUDY OF THE TRICARBOXYLIC-ACID CYCLE
    KATZ, J
    BIOCHEMICAL JOURNAL, 1989, 263 (03) : 997 - 997
12345