CATALYTIC PERFORMANCE IN HYDRODESULFURIZATION OF THIOPHENE AND IR INVESTIGATION OF CO AND NO ADSORPTION OVER CO-MO/AL2O3 AND RU-CO-MO/AL2O3 CATALYSTS

被引：7
|
作者：
XIAO, FS [1 ]
XIN, Q [1 ]
GUO, XX [1 ]
机构：
[1] CHINESE ACAD SCI,DALIAN INST CHEM PHYS,NATL LAB CATALYSIS,DALIAN 116023,PEOPLES R CHINA
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1992年 / 46卷 / 02期
关键词：
Bathochromic Shift - Hydrodesulfurization - Ruthenium Cobalt Molybdenum Aluminum Oxide - Thiophene;
D O I：
10.1007/BF02070957
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new Ru-Co-Mo/Al2O3 catalyst has been prepared by impregnation of Ru salt as a secondary promoter onto Co-Mo/Al2O3 catalyst, and it was found that the Ru-Co-Mo/Al2O3 exhibited higher activity than Co-Mo/Al2O3 in hydrodesulfurization of thiophene to hydrocarbons. Ir studies on Ru-Co-Mo/Al2O3 revealed that the CO and NO adspecies increased significantly in intensities and displayed a bathochromic shift in frequencies, as compared with Co-Mo/Al2O3.
引用
收藏
页码：351 / 357
页数：7
相关论文
共 50 条
  • [21] THERMAL-STABILITY OF CO-MO/AL2O3 HYDRODESULFURIZATION CATALYST
    WALENDZIEWSKI, J
    APPLIED CATALYSIS, 1989, 52 (03): : 181 - 192
  • [22] SULFIDABILITY AND HDS ACTIVITY OF CO-MO/AL2O3 CATALYSTS
    SCHEFFER, B
    VANOERS, EM
    ARNOLDY, P
    DEBEER, VHJ
    MOULIJN, JA
    APPLIED CATALYSIS, 1986, 25 (1-2): : 303 - 311
  • [23] ADSORPTION AND SPILLOVER OF HYDROGEN IN THE CO-MO/AL2O3 SYSTEM
    ROZANOV, VV
    TSAO, YM
    KRYLOV, OV
    KINETICS AND CATALYSIS, 1993, 34 (01) : 147 - 151
  • [24] In-situ FTIR study of CO adsorption on Co-Mo/Al2O3 hydrodesulphurization catalysts
    Yuan Hui
    Sun Shu-ling
    Zheng Ai-guo
    Xu Guang-tong
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28 (09) : 2044 - 2047
  • [25] Effect of phosphorus addition on the active sites of a Co-Mo/Al2O3 catalyst for the hydrodesulfurization of thiophene
    Usman
    Yamamoto, Tomoya
    Kubota, Takeshi
    Okamoto, Yasuaki
    APPLIED CATALYSIS A-GENERAL, 2007, 328 (02) : 219 - 225
  • [26] ACTIVITY DEVELOPMENT OF UNSUPPORTED AND AL2O3 SUPPORTED CO-MO CATALYSTS IN THIOPHENE HDS
    KORANYI, T
    DOBROVOLSZKY, M
    PAAL, Z
    ACTA CHIMICA HUNGARICA-MODELS IN CHEMISTRY, 1987, 124 (01): : 73 - 82
  • [27] Deactivation of Mo/Al2O3 and NiMo/Al2O3 catalysts during hydrodesulfurization of thiophene
    Vogelaar, BM
    Steiner, P
    van Langeveld, AD
    Eijsbouts, S
    Moulijn, JA
    APPLIED CATALYSIS A-GENERAL, 2003, 251 (01) : 85 - 92
  • [28] Promoter Nature Effect on the Sensitivity of Ni-Mo/Al2O3, Co-Mo/Al2O3, and Ni-Co-Mo/Al2O3 Catalysts to Dodecanoic Acid in the Co-Hydrotreating of Dibenzothiophene and Naphthalene
    Koklyukhin, A. S.
    Mozhaev, A. V.
    Sal'nikov, V. A.
    Nikul'shin, P. A.
    KINETICS AND CATALYSIS, 2017, 58 (04) : 463 - 470
  • [29] Effect of H2S inhibition on the hydrodechlorination of polychlorinated biphenyls over Mo/Al2O3 and Co-Mo/Al2O3 catalysts
    De La Rosa, Marjorie
    Betancourt, Paulino
    Diaz, Armando
    Brito, Joaquin L.
    Pinto-Castilla, Susana
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2014, 111 (01) : 277 - 292
  • [30] Kinetics of Thiophene Hydrodesulfurization on Mo-Ni-Co/Al2O3 Catalyst
    朱泽霖
    李承烈
    华东理工大学学报(自然科学版), 1996, (04) : 412 - 416
12345