PREPARATION AND CRYSTAL-STRUCTURE OF TLCU[CUO2]

被引：7
作者：
ADAM, A
FELSERWENZ, C
SCHUSTER, HU
HOPPE, R
机构：
[1] UNIV GIESSEN,INST ANORGAN & ANALYT CHEM 1,HEINRICH BUFF RING 58,W-6300 GIESSEN,GERMANY
[2] UNIV COLOGNE,INST ANORGAN CHEM,W-5000 COLOGNE 41,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 605卷 / 14期
关键词：
TLCU[CUO2; SYNTHESIS; CRYSTAL STRUCTURE; LATTICE ENERGY;
D O I：
10.1002/zaac.19916050119
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By reaction of Tl2O3 and Cu2O in a sealed copper-type TlCu[CuO2] was synthesized; the orthorhombically bodycentered crystallizing compound forms a new structure type, space group Imma (no. 74), with the lattice constants a = 552.5 pm, b = 605.2 pm, c = 896.4 pm. The Madelung Part of Lattice Energy, MAPLE, as well as Effective Coordination Numbers, ECoN, these via Mean Effective Ionic Radii, MEFIR, were calculated.
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页码：157 / 162
页数：6
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