FROM DISUBSTITUTED ACETYLENES TO TRISUBSTITUTED OLEFINS - AN APPLICATION

被引：18
|
作者：
BENECHIE, M [1 ]
SKRYDSTRUP, T [1 ]
KHUONGHUU, F [1 ]
机构：
[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 51期
关键词：
D O I：
10.1016/0040-4039(91)80527-D
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The transformation of disubstituted acetylenes to trisubstituted olefins was studied in order to obtain precursors of the north-eastern part of maytansine. Depending on the starting material, a trans or a cis stannylation reaction could lead to the olefin of the desired stereochemistry
引用
收藏
页码：7535 / 7538
页数：4
相关论文
共 50 条
  • [41] Reductive decomplexation of biscobalthexacarbonyl acetylenes into olefins
    Hosokawa, S
    Isobe, M
    TETRAHEDRON LETTERS, 1998, 39 (17) : 2609 - 2612
  • [42] TRISUBSTITUTED OLEFINS VIA ESTER-DERIVED (SILYLOXY)ACETYLENES - A HIGHLY STEREOSELECTIVE ALTERNATIVE TO THE HORNER-WADSWORTH-EMMONS REACTION
    KOWALSKI, CJ
    SAKDARAT, S
    JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (07) : 1977 - 1979
  • [43] Markovnikov-Selective Hydrothiolation of Styrenes: Application to the Synthesis of Stereodefined Trisubstituted Olefins
    Savolainen, Markku A.
    Wu, Jimmy
    ORGANIC LETTERS, 2013, 15 (14) : 3802 - 3804
  • [44] PHOSPHORYLATION OF TRISUBSTITUTED OLEFINS BY PHOSPHORUS PENTACHLORIDE
    ROZINOV, VG
    MIKHNEVI.VV
    GRECHKIN, EF
    ZHURNAL OBSHCHEI KHIMII, 1970, 40 (04): : 935 - &
  • [45] Synthesis and properties of polymers from disubstituted acetylenes with chiral pinanyl groups
    Aoki, T
    Kobayashi, Y
    Kaneko, T
    Oikawa, E
    Yamamura, Y
    Fujita, Y
    Teraguchi, M
    Nomura, R
    Masuda, T
    MACROMOLECULES, 1999, 32 (01) : 79 - 85
  • [46] Highly enantioselective cyclopropanation of trisubstituted olefins
    Jun Li
    Long Zheng
    Hao Chen
    Lijia Wang
    Xiu-Li Sun
    Jun Zhu
    Yong Tang
    Science China(Chemistry), 2018, (05) : 526 - 530
  • [47] The isolation of 1,2-diketones from the ozonization of disubstituted acetylenes
    Jacobs, TL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1936, 58 : 2272 - 2273
  • [48] SYNTHESIS OF DISUBSTITUTED AND TRISUBSTITUTED FURAN DERIVATIVES
    ROBBA, M
    ZALUSKI, MC
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1969, 268 (21): : 1884 - &
  • [49] REGIOSPECIFIC AND STEREOSELECTIVE ISOMERIZATION OF TRISUBSTITUTED OLEFINS
    KRIEF, A
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1972, 275 (08): : 459 - &
  • [50] PHOSPHORYLATION OF TRISUBSTITUTED OLEFINS WITH PHOSPHORUS PENTACHLORIDE
    ROZINOV, VG
    MIKHNEVI.VV
    GRECHKIN, EF
    JOURNAL OF GENERAL CHEMISTRY USSR, 1970, 40 (04): : 915 - &
12345