FROM DISUBSTITUTED ACETYLENES TO TRISUBSTITUTED OLEFINS - AN APPLICATION

被引：18
|
作者：
BENECHIE, M [1 ]
SKRYDSTRUP, T [1 ]
KHUONGHUU, F [1 ]
机构：
[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 51期
关键词：
D O I：
10.1016/0040-4039(91)80527-D
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The transformation of disubstituted acetylenes to trisubstituted olefins was studied in order to obtain precursors of the north-eastern part of maytansine. Depending on the starting material, a trans or a cis stannylation reaction could lead to the olefin of the desired stereochemistry
引用
收藏
页码：7535 / 7538
页数：4
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