FROM DISUBSTITUTED ACETYLENES TO TRISUBSTITUTED OLEFINS - AN APPLICATION

被引:18
|
作者
BENECHIE, M [1 ]
SKRYDSTRUP, T [1 ]
KHUONGHUU, F [1 ]
机构
[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE
关键词
D O I
10.1016/0040-4039(91)80527-D
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The transformation of disubstituted acetylenes to trisubstituted olefins was studied in order to obtain precursors of the north-eastern part of maytansine. Depending on the starting material, a trans or a cis stannylation reaction could lead to the olefin of the desired stereochemistry
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页码:7535 / 7538
页数:4
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