STRUCTURAL AND STEREOCHEMICAL FACTORS IN THE MASS-SPECTROMETRY OF THE SUBSTITUTED CYCLOPENTANES .1. MONOALKYLCYCLOPENTANES AND DIALKYLCYCLOPENTANES

被引：1
作者：
GOLOVKINA, LS
RUSINOVA, GV
PETROV, AA
机构：
[1] Institute of Geology and Fossil Fuel Development, Ministry of the Petroleum Industry and the Academy of Sciences of the USSR, Moscow
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1979年 / 28卷 / 01期
关键词：
D O I：
10.1007/BF00925398
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1. The mono- and dialkylcyclopentanes fragment in the same manner under electron impact. 2. The m/e 68 and 69 doublet is characteristic of the monoalkylcyclopentanes and can be used for their identification. 3. The mass spectra of the trans and cis isomers of the 1,3-dialkylcyclopentanes are identical. The spectra of the 1,2-substituted compounds differ in the intensities of the molecular ion and C4H8+ ion peaks. 4. The spectra of the structural isomers show clearcut differences in the intensities of the M+., [M-RH]+., and C5H7+ ion peaks which can be used in establishing substitution types. © 1979 Plenum Publishing Corporation.
引用
收藏
页码：58 / 62
页数：5
相关论文
共 50 条
  • [31] MASS-SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .233. STEREOCHEMICAL DEPENDENCE OF RETRO-DIELS-ALDER REACTION
    HAMMERUM, S
    DJERASSI, C
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (17) : 5806 - 5807
  • [32] PHYSICAL METHODS .1. ORGANIC MASS-SPECTROMETRY
    JOHNSTONE, RA
    MELLON, FA
    ANNUAL REPORTS ON THE PROGRESS OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY, 1972, 69 : 7 - 18
  • [33] PRINCIPLES OF THE THEORY FOR QUADRUPOLE MASS-SPECTROMETRY .1.
    SHERETOV, EP
    ZHURNAL TEKHNICHESKOI FIZIKI, 1979, 49 (01): : 34 - 40
  • [34] PHYSICAL METHODS AND TECHNIQUES .1. MASS-SPECTROMETRY
    JARMAN, M
    ANNUAL REPORTS ON THE PROGRESS OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY, 1979, 76 : 3 - 12
  • [35] MASS-SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .250. CHARACTERISTIC FRAGMENTATIONS OF CHOLESTEROL ACETATE
    PARTRIDGE, LG
    DJERASSI, C
    JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (17) : 2799 - 2805
  • [36] PHYSICAL METHODS .1. ORGANIC MASS-SPECTROMETRY
    JOHNSTONE, RAW
    MELLON, FA
    ANNUAL REPORTS ON THE PROGRESS OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY, 1973, 70 : 7 - 21
  • [37] MASS-SPECTROMETRY OF HAPLOPHYLLUM AND FOLIFINE ALKALOIDS .1.
    RASHKES, YV
    FAIZUTDI.ZS
    YUNUSOV, SY
    KHIMIYA PRIRODNYKH SOEDINENII, 1970, (01): : 107 - &
  • [38] PHYSICAL METHODS .1. ORGANIC MASS-SPECTROMETRY
    JOHNSTON.RA
    MELLON, FA
    ANNUAL REPORTS ON THE PROGRESS OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY, 1971, 68 : 5 - &
  • [39] POSITRON IONIZATION MASS-SPECTROMETRY .1. INSTRUMENTATION
    DONOHUE, DL
    HULETT, LD
    MCLUCKEY, SA
    GLISH, GL
    MCKOWN, HS
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1990, 97 (03): : 227 - 236
  • [40] MASS-SPECTROMETRY IN STEREOCHEMICAL PROBLEMS .6. THE CASE OF MONO-SUBSTITUTED AND DISUBSTITUTED NORBORNANCES
    CURCURUTO, O
    FAVRETTO, D
    TRALDI, P
    AJO, D
    CATIVIELA, C
    MAYORAL, JA
    LOREZ, MP
    FRAILE, JM
    GARCIA, JI
    ORGANIC MASS SPECTROMETRY, 1991, 26 (11): : 977 - 984
12345