2ND-HARMONIC GENERATION AS A PROBE OF ROTATIONAL MOBILITY IN POLED POLYMERS

被引:74
作者
BOYD, GT
FRANCIS, CV
TREND, JE
ENDER, DA
机构
[1] 3M Corporate Research Laboratory, St. Paul, MI, 55144, 201-2N-19
关键词
D O I
10.1364/JOSAB.8.000887
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Second-harmonic generation was used to determine the rotational mobility of dopants in polymer hosts aligned by an electric field as a function of temperature and of dopant molecular volume. A free-volume model is used to interpret the results and to estimate the average free volume surrounding the dopants.
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页码:887 / 894
页数:8
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