ELECTRONIC-ENERGY TRANSFER IN A SUPRAMOLECULAR SPECIES CONTAINING THE [RU(BPY)(3)](2+), [OS(BPY)(3)](2+), AND ANTHRACENE CHROMOPHORIC UNITS

被引：104

作者：

BELSER, P ^{[1
]}

DUX, R ^{[1
]}

BAAK, M ^{[1
]}

DECOLA, L ^{[1
]}

BALZANI, V ^{[1
]}

机构：

[1] UNIV BOLOGNA, DIPARTIMENTO CHIM G CIAMICIAN, I-40126 BOLOGNA, ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1995年 / 34卷 / 05期

关键词：

CHARGE TRANSFER COMPLEXES; ENERGY TRANSFER; PHOTOCHEMISTRY; SUPRAMOLECULAR CHEMISTRY; TRANSITION METAL COMPOUNDS;

D O I：

10.1002/anie.199505951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A very efficient and fast energy transfer (k = 4.7 × 108 s−1) is observed from the Ru‐ to the Os‐based moiety in 1. In the presence of oxygen a photoreaction occurs that leads to a strong decrease (about 80 times) in the rate of the energy transfer process. R  CH2C6H5, bpy = 2,2′‐bipyridine. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：595 / 598

页数：4

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