SYNTHESIS AND CRYSTAL-STRUCTURE OF RAMSDELLITE-TYPE LI0.5TIO2

被引：31

作者：

AKIMOTO, J ^{[1
]}

GOTOH, Y ^{[1
]}

SOHMA, M ^{[1
]}

KAWAGUCHI, K ^{[1
]}

OOSAWA, Y ^{[1
]}

TAKEI, H ^{[1
]}

机构：

[1] UNIV TOKYO,INST SOLID STATE PHYS,MINATO KU,TOKYO 106,JAPAN

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1994年 / 110卷 / 01期

关键词：

D O I：

10.1006/jssc.1994.1149

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Black single crystals of Li0.5TiO2 were synthesized by the reaction of lithium metal and titanium dioxide at 1473 K. It crystallizes in the orthorhombic ramsdellite-type structure, space group Pbnm with a = 5.0356(6), b = 9.6377(8), c = 2.9484(7) angstrom, V = 143.09(4) angstrom3, and Z = 4. The structure was determined from a single-crystal X-ray study and refined to the conventional values R = 0.038 and wR =0.046 for 744 independent reflections. The distorted octahedral sites are occupied only by Ti atoms, and a Li atom is located at one tetrahedral tunnel site with the occupancy factor of 0.45(2). (C) 1994 Academic Press, Inc.

引用

页码：150 / 155

页数：6

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