ELECTRONIC-SPECTRA OF METAL CLUSTER MOLECULES

被引：0
|
作者：
BENFIELD, RE [1 ]
MAYDWELL, AP [1 ]
VANRUITENBEEK, JM [1 ]
VANLEEUWEN, DA [1 ]
机构：
[1] LEIDEN UNIV,KAMERLINGH ONNES LAB,2300 RA LEIDEN,NETHERLANDS
来源：
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS | 1993年 / 26卷
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The electronic absorption spectra (UV-visible-NIR) of a range of molecular metal cluster compounds, including new spectra of Pt309(phen*)36O28 in solution and Au55(PPh3)12Cl6 in the solid state, are discussed and compared with the spectra of colloidal particles of the corresponding metals. We consider frontier orbital separations, the development of 'interband' absorptions, the possible appearance of molecular plasma resonances, and charge-transfer in the solid state.
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页码：S4 / S7
页数：4
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