REACTIONS OF TITANOCENTRIHALIDES WITH TRIS(TRIMETHYLSTANNYL)AMINE

被引：29

作者：

BAI, Y ^{[1
]}

ROESKY, HW ^{[1
]}

SCHMIDT, HG ^{[1
]}

NOLTEMEYER, M ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1992年 / 47卷 / 05期

关键词：

CLEAVAGE OF TIN-NITROGEN BONDS; TITANOCENHALIDES;

D O I：

10.1515/znb-1992-0501

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new route for the preparation of (Me3Ge)3N (2a) using Me3GeCl and (Me3Sn)3N is described. Cp'TiCl3 (Cp' = Me5C5 (1a) and M3SiC5H4 (1b)) reacts with (Me3Sn)3N to yield (Cp'TiClNSnMe3)2 (3a) and (3b). (Me5C5TiFNSnMe3)2 (3c) is formed when Me5C5TiF3 is treated with (Me3Sn)3N. The X-ray structures of 3a and (Me3SiC5H4TiClNtBu)2 (5) are reported. 3a and 5 consist in the solid state of four-membered Ti2N2 rings with the substituents in different positions.

引用

页码：603 / 608

页数：6

共 32 条

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[32] SYNTHESIS AND CRYSTAL-STRUCTURES OF 3 4-MEMBERED RING COMPOUNDS CONTAINING PN2TI SKELETONS [J].

WITT, M ;

ROESKY, HW ;

STALKE, D ;

PAUER, F ;

HENKEL, T ;

SHELDRICK, GM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (11) :2173-2177

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