REACTIONS OF TITANOCENTRIHALIDES WITH TRIS(TRIMETHYLSTANNYL)AMINE

被引：29
作者：
BAI, Y [1 ]
ROESKY, HW [1 ]
SCHMIDT, HG [1 ]
NOLTEMEYER, M [1 ]
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1992年 / 47卷 / 05期
关键词：
CLEAVAGE OF TIN-NITROGEN BONDS; TITANOCENHALIDES;
D O I：
10.1515/znb-1992-0501
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new route for the preparation of (Me3Ge)3N (2a) using Me3GeCl and (Me3Sn)3N is described. Cp'TiCl3 (Cp' = Me5C5 (1a) and M3SiC5H4 (1b)) reacts with (Me3Sn)3N to yield (Cp'TiClNSnMe3)2 (3a) and (3b). (Me5C5TiFNSnMe3)2 (3c) is formed when Me5C5TiF3 is treated with (Me3Sn)3N. The X-ray structures of 3a and (Me3SiC5H4TiClNtBu)2 (5) are reported. 3a and 5 consist in the solid state of four-membered Ti2N2 rings with the substituents in different positions.
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页码：603 / 608
页数：6
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