X-ray photoelectron spectroscopy study of the interaction of lithium with graphene

被引:6
作者
Bulusheva, Lyubov G. [1 ]
Okotrub, Alexander V. [1 ]
Yashina, Lada V. [2 ]
Velasco-Velez, Juan J. [3 ]
Usachov, Dmitry Yu. [4 ]
Vyalikh, Denis V. [5 ,6 ,7 ]
机构
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Moscow MV Lomonosov State Univ, Leninskie Gory 1-3, Moscow 199991, Russia
[3] Max Planck Inst Chem Energy Convers, Dept Heterogeneous React, Stiftstr 34-36, D-45470 Mulheim, Germany
[4] St Petersburg State Univ, Dept Phys, 7-9 Univ Skaya Nab, St Petersburg 199034, Russia
[5] Donostia Int Phys Ctr DIPC, Dept Fis Mat, San Sebastian 20080, Spain
[6] Donostia Int Phys Ctr DIPC, CFM MPC UPV EHU, San Sebastian 20080, Spain
[7] Basque Fdn Sci, Ikerbasque, Bilbao 48011, Spain
关键词
CVD graphene; graphene/metal interface; nitrogen doping; batteries; X-ray photoelectron spectroscopy; synchrotron radiation;
D O I
10.1515/psr-2018-0042
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Graphene-like nanostructures, solely or in combination with redox active compounds, are an important component of battery electrodes. Design of effective electrode materials requires a deep understanding of electrochemical reactions occurring at graphene surfaces. The methods of X-ray photoelectron spectroscopy (XPS) are very helpful in such research, providing the composition of studied samples and electronic state of individual elements. In this chapter, we demonstrate advantages of XPS for monitoring of chemical vapor deposition graphene growth and lithium penetration under graphene layers, disclosing of interactions with metals and interface states.
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页数:9
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