STRUCTURE OF 3,3,5,5-TETRAMETHYL-7-OXABICYCLO[4.1.0]HEPTAN-1-YL METHYLSULFOXIDE RSSS(OR SSRR)

被引：4
|
作者：
LECLAIRE, A [1 ]
BARILLIER, D [1 ]
VAZEUX, M [1 ]
机构：
[1] UNIV CAEN,UA 480,COMPOSES THIOORGAN LAB,F-14032 CAEN,FRANCE
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷
关键词：
D O I：
10.1107/S0108270190003419
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C11H20O2S, M(r) = 216.34, monoclinic, P2(1)/c, a = 12.538 (1), b = 8.587 (2), c = 11.411 (4) angstrom, beta = 90.71 (2)degrees, V = 1228.4 (8) angstrom 3, Z = 4, D(x) = 1.17 Mg m-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 0.24 mm-1, F(000) = 472, T = 294 K, R = 0.039, wR = 0.039 for 1412 independent reflections. Simple C-C bonds in the six-membered ring are shorter near the epoxide ring. The epoxide and sulfinyl O atoms are syn with respect to the S-C bond. The cyclohexyl ring has a half-chair conformation. The crystalline structure appears to be in accord with H-1 NMR indicating that the relative configurations of the molecule are identical in both the solid state and solution.
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页码：146 / 148
页数：3
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