PREPARATION OF POLYANILINE BY ELECTROCHEMICAL POLYMERIZATION OF ANILINE IN ACETONITRILE SOLUTION

被引：20
|
作者：
MIRAS, MC
BARBERO, C
HAAS, O
机构：
[1] Paul Scherrer Institut
来源：
SYNTHETIC METALS | 1991年 / 43卷 / 1-2期
关键词：
D O I：
10.1016/0379-6779(91)91243-4
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Aniline can be electropolymerized in neutral and dry acetonitrile solution by potentio-dynamic oxidation. This result suggests that protonation of aniline is not necessary for the polymerization. The resulting polymer is electroactive and stable. Its morphology and structure is similar to that of poly(aniline) obtained in aqueous HClO4 solution but more compact. The voltammetric response, either in aqueous or nonaqueous solution, shows two oxidation peaks with a charge ratio greater than one between the first and the second.
引用
收藏
页码：3081 / 3084
页数：4
相关论文
共 50 条
  • [1] Preparation and electrochemical analysis of graphene/polyaniline composites prepared by aniline polymerization
    Jieun Kim
    Seok Kim
    Research on Chemical Intermediates, 2014, 40 : 2519 - 2525
  • [2] Preparation and electrochemical analysis of graphene/polyaniline composites prepared by aniline polymerization
    Kim, Jieun
    Kim, Seok
    RESEARCH ON CHEMICAL INTERMEDIATES, 2014, 40 (07) : 2519 - 2525
  • [3] Electrochemical polymerization of aniline in phosphoric acid and the properties of polyaniline
    Mu, SL
    Kong, Y
    Wu, J
    CHINESE JOURNAL OF POLYMER SCIENCE, 2004, 22 (05) : 405 - 415
  • [4] ELECTROCHEMICAL POLYMERIZATION OF ANILINE IN PHOSPHORIC ACID AND THE PROPERTIES OF POLYANILINE
    穆绍林
    Chinese Journal of Polymer Science, 2004, (05) : 405 - 415
  • [5] Interconversion of polarons and bipolarons of polyaniline during the electrochemical polymerization of aniline
    Mu, SL
    Kan, JQ
    Lu, JT
    Lin, Z
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 446 (1-2): : 107 - 112
  • [6] THE EFFECT OF ANIONS OF SUPPORTING ELECTROLYTE ON THE ELECTROCHEMICAL POLYMERIZATION OF ANILINE AND THE PROPERTIES OF POLYANILINE
    WANG, BC
    TANG, JS
    WANG, FS
    SYNTHETIC METALS, 1986, 13 (04) : 329 - 334
  • [7] MODIFIED POLYANILINE THROUGH SIMULTANEOUS ELECTROCHEMICAL POLYMERIZATION OF ANILINE AND METANILIC ACID
    LEE, JY
    CUI, CQ
    SU, XH
    ZHOU, MS
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 360 (1-2): : 177 - 187
  • [8] Polymerization of aniline on polyaniline membranes
    Blinova, Natalia V.
    Stejskal, Jaroslav
    Trchova, Miroslava
    Ciric-Marjanovic, Gordana
    Sapurina, Irina
    JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (10): : 2440 - 2448
  • [9] The kinetic behavior for the electrochemical polymerization of aniline in aqueous solution
    Mu, SL
    Chen, CX
    Wang, JM
    SYNTHETIC METALS, 1997, 88 (03) : 249 - 254
  • [10] Preparation of polyaniline nanofibers using the organic solution of aniline as seed
    Xing, Shuangxi
    Zheng, Hongwei
    E-POLYMERS, 2008,
12345