ZEEMAN SPLITTINGS OF THE 2 LOWEST EXCITED-STATES OF [RU(BPY)3](PF6)2

被引：16
|
作者：
BRAUN, D [1 ]
GALLHUBER, E [1 ]
YERSIN, H [1 ]
机构：
[1] UNIV REGENSBURG, INST PHYS & THEORET CHEM, W-8400 REGENSBURG, GERMANY
来源：
CHEMICAL PHYSICS LETTERS | 1990年 / 171卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(90)80061-H
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
For [Ru(bpy)3](PF6)2, the splittings of the two lowest excited electronic states could be measured under magnetic fields (Zeeman effect). The splittings of both states increase with the magnetic-field strength to 3 ± 0.5 cm-1 at B = 6 T. It is concluded that at B equal zero, the parent terms of these two states cannot be classified as originating from a situation in which one electron is localized on one ligand. © 1990.
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页码：122 / 126
页数：5
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