ZEEMAN SPLITTINGS OF THE 2 LOWEST EXCITED-STATES OF [RU(BPY)3](PF6)2

被引：16

作者：

BRAUN, D ^{[1
]}

GALLHUBER, E ^{[1
]}

YERSIN, H ^{[1
]}

机构：

[1] UNIV REGENSBURG, INST PHYS & THEORET CHEM, W-8400 REGENSBURG, GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 171卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(90)80061-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For [Ru(bpy)3](PF6)2, the splittings of the two lowest excited electronic states could be measured under magnetic fields (Zeeman effect). The splittings of both states increase with the magnetic-field strength to 3 ± 0.5 cm-1 at B = 6 T. It is concluded that at B equal zero, the parent terms of these two states cannot be classified as originating from a situation in which one electron is localized on one ligand. © 1990.

引用

页码：122 / 126

页数：5

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