ZEEMAN SPLITTINGS OF THE 2 LOWEST EXCITED-STATES OF [RU(BPY)3](PF6)2

被引：16

作者：

BRAUN, D ^{[1
]}

GALLHUBER, E ^{[1
]}

YERSIN, H ^{[1
]}

机构：

[1] UNIV REGENSBURG, INST PHYS & THEORET CHEM, W-8400 REGENSBURG, GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 171卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(90)80061-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For [Ru(bpy)3](PF6)2, the splittings of the two lowest excited electronic states could be measured under magnetic fields (Zeeman effect). The splittings of both states increase with the magnetic-field strength to 3 ± 0.5 cm-1 at B = 6 T. It is concluded that at B equal zero, the parent terms of these two states cannot be classified as originating from a situation in which one electron is localized on one ligand. © 1990.

引用

页码：122 / 126

页数：5

共 28 条

[1] SPECTROSCOPIC AND MAGNETIC EVIDENCE FOR MULTIPLE-STATE EMISSION FROM TRIS(2,2'-BIPYRIDINE) RUTHENIUM (II) SULFATE
BAKER, DC
CROSBY, GA
[J]. CHEMICAL PHYSICS, 1974, 4 (03) : 428 - 433
[2] VIBRATIONAL SPECTROSCOPY OF THE ELECTRONICALLY EXCITED-STATE .5. TIME-RESOLVED RESONANCE RAMAN-STUDY OF TRIS(BIPYRIDINE)RUTHENIUM(II) AND RELATED COMPLEXES - DEFINITIVE EVIDENCE FOR THE LOCALIZED MLCT STATE
BRADLEY, PG
KRESS, N
HORNBERGER, BA
DALLINGER, RF
WOODRUFF, WH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (25) : 7441 - 7446
[3] EXCITON TRAPPING AND SELF-TRAPPING IN MOLECULAR-CRYSTALS
CRAIG, DP
DISSADO, LA
WALMSLEY, SH
[J]. CHEMICAL PHYSICS LETTERS, 1977, 46 (01) : 191 - 196
[4] MAGNETIC-FIELD EFFECTS IN THE LOW-TEMPERATURE POLARIZED EMISSION AND ABSORPTION-SPECTRA OF SINGLE-CRYSTAL [RU(BPY)3](PF6)2
GALLHUBER, E
HENSLER, G
YERSIN, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (16) : 4818 - 4822
[5] GALLHUBER E, 1986, 11 IUPAC S PHOT LISB, P384
[6] ENERGY BARRIER BETWEEN SELF-TRAPPED AND DELOCALIZED EXCITON-STATES IN QUASI ONE-DIMENSIONAL TETRACYANOPLATINATES .2.
GLIEMANN, G
HOLZAPFEL, W
YERSIN, H
[J]. JOURNAL DE PHYSIQUE, 1985, 46 (C-7): : 129 - 133
[7] SPIN HAMILTONIAN FOR EVEN-ELECTRON SYSTEMS HAVING EVEN MULTIPLICITY
GRIFFITH, JS
[J]. PHYSICAL REVIEW, 1963, 132 (01): : 316 - &
[8] SYMMETRY ASSIGNMENTS OF LOWEST CT EXCITED-STATES OF RUTHENIUM (II) COMPLEXES VIA A PROPOSED ELECTRONIC COUPLING MODEL
HARRIGAN, RW
CROSBY, GA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (07) : 3468 - 3476
[9] MAGNETIC-FIELD INDUCED ABSORPTION OF ZERO-PHONON LINES IN [RU(BPY)3](PF6)2 AND [RU(BPY)3](CLO4)2 SINGLE-CRYSTALS
HENSLER, G
GALLHUBER, E
YERSIN, H
[J]. INORGANIC CHEMISTRY, 1987, 26 (11) : 1641 - 1642
[10] HOT LUMINESCENCE OF SELF-TRAPPED EXCITONS IN ALKALI-HALIDE CRYSTALS
HIZHNYAKOV, VV
PLEKHANOV, VG
SHEPELEV, VV
ZAVT, GS
[J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1981, 108 (02): : 531 - 540

← 1 2 3 →