ACYLATED ANTHOCYANINS OF CLITORIA-TERNATEA FLOWERS AND THEIR ACYL MOIETIES

被引:63
作者
TERAHARA, N
SAITO, N
HONDA, T
TOKI, K
OSAJIMA, Y
机构
[1] MEIJI GAKUIN UNIV,CHEM LAB,TOTSUKA KU,YOKOHAMA 224,JAPAN
[2] HOSHI COLL PHARM,SHINAGAWA KU,TOKYO 142,JAPAN
[3] MINAMI KYUSHU UNIV,COLL HORT,DEPT HORT,TAKANABE,MIYAZAKI 884,JAPAN
[4] KYUSHU UNIV,FAC AGR,DEPT FOOD SCI & TECHNOL,FUKUOKA 812,JAPAN
关键词
6-O-malonyl-d-glucopyranose; acylated anthocyanins; Clitoria ternatea; E-4-O-β-d-glucopyranosyl-p-coumaric acid; FABMS; flowers; Leguminosae; NMR; ternatin A1; A2; B1; B2; D1 and D2;
D O I
10.1016/0031-9422(90)80053-J
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Two acyl moieties, prepared by alkaline deacylation or H2O2 oxidation of ternatin mixture from Clitoria ternatea flowers, were determined as E-4-O-β-d-glucopyranosyl-p-coumaric acid and 6-O-malonyl-d-glucopyranose respectively through FABMS and NMR. Furthermore, six ternatins A1, A2, B1, B2, D1 and D2 in C. ternatea flowers were isolated by reversed phase HPLC and their structures were partly characterized as highly acylated delphinidin derivatives. © 1990.
引用
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页码:949 / 953
页数:5
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