REACTION OF THE FLUORIDE ANION WITH ACETONITRILE, CHLOROFORM AND METHYLENE-CHLORIDE

被引：88

作者：

CHRISTE, KO

WILSON, WW

机构：

[1] Rocketdyne, a Division of Rockwell International Corporation, Canoga Park

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 47卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)80453-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

19F and 1H NMR spectra of the F- anion in CH3CN and CD3CN solutions show that the F- anion can abstract a proton from CH3CN resulting in the slow formation of the bifluoride and acetonitrile anions. With chloroform or methylene chloride the F- anion undergoes halogen exchange reactions at room temperature. These reactions demonstrate the exceptional reactivity of the free fluoride anion when present as a highly soluble salt. © 1990.

引用

页码：117 / 120

页数：4

共 13 条

[1]

[Anonymous], 1969, ORGANIC FLUORINE CHE

[2] SYNTHESIS, VIBRATIONAL-SPECTRA, AND CRYSTAL-STRUCTURE ANALYSIS OF DI AND TRIFLUORO-TETRAMETHYLAMMONIUM SALTS [J].