SYNTHESES OF RHODIUM AND IRIDIUM (OCTAETHYLPORPHYRINATO)METAL DIMERS FROM TEMPO

被引：29
作者：
CHAN, KS [1 ]
LEUNG, YB [1 ]
机构：
[1] UNIV CHICAGO,DEPT CHEM,CHICAGO,IL 60637
来源：
INORGANIC CHEMISTRY | 1994年 / 33卷 / 14期
关键词：
D O I：
10.1021/ic00092a028
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Rh2(OEP)2 and Ir2(OEP)2 metal dimers were synthesized from Rh(OEP)H and Ir(OEP)H using TEMPO. 2M(OEP)H + 2TEMPO --> M2(OEP)2 + 2TEMPOH 90% M = Rh, Ir
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页码：3187 / 3187
页数：1
相关论文
共 8 条
[1]   ELECTROCATALYTIC 4-ELECTRON REDUCTION OF DIOXYGEN BY IRIDIUM PORPHYRINS ADSORBED ON GRAPHITE [J].
COLLMAN, JP ;
KIM, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) :7847-7849
[2]  
DELROSSI KJ, 1986, J CHEM SOC CHEM COMM, P16
[3]   CALORIMETRIC AND EQUILIBRIUM STUDIES ON SOME STABLE NITROXIDE AND IMINOXY RADICALS - APPROXIMATE O-H BOND-DISSOCIATION ENERGIES IN HYDROXYLAMINES AND OXIMES [J].
MAHONEY, LR ;
MENDENHA.GD ;
INGOLD, KU .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (26) :8610-8614
[4]  
OGOSHI H, 1982, J CHEM SOC P1, P983
[5]  
OGOSHI H, 1987, J ORGANOMET CHEM, V159, P317
[6]   INSERTION AND OXIDATIVE ADDITION-REACTIONS OF RHODIUM PORPHYRIN COMPLEXES - NOVEL FREE-RADICAL CHAIN MECHANISMS [J].
PAONESSA, RS ;
THOMAS, NC ;
HALPERN, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (14) :4333-4335
[7]   OXIDATION OF HYDROXYLAMINES TO NITROXYL RADICALS WITH FREMYS SALT - NITROXYL ALDEHYDES [J].
SCHLUDE, H .
TETRAHEDRON, 1973, 29 (23) :4007-4011
[8]   ACTIVATION OF METHANE AND TOLUENE BY RHODIUM(II) PORPHYRIN COMPLEXES [J].
WAYLAND, BB ;
BA, S ;
SHERRY, AE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) :5305-5311
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