CRYSTAL-GROWTH, CRYSTAL-STRUCTURE, OPTICAL, ELECTROOPTIC AND ELECTROSTRICTIVE PROPERTIES OF THE ORTHORHOMBIC TARTRATO-ANTIMONATE-(III) NITRATE KZN[SB2((+)-C4H2O6)2]NO3.5H2O (KZNSBTN)

被引：6

作者：

BOHATY, L ^{[1
]}

FROHLICH, R ^{[1
]}

机构：

[1] ENRAF,NONIUS,D-42653 SOLINGEN,GERMANY

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1994年 / 209卷 / 01期

关键词：

CRYSTAL GROWTH; CRYSTAL STRUCTURE; ELECTROOPTICS; ELECTROSTRICTION;

D O I：

10.1524/zkri.1994.209.1.14

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

KZnSbTN is an example from the large acentric double salt-like family of tartrato-antimonates. Its crystal structure was determined from single-crystal X-ray diffraction data (orthorhombic, P2(1)2(1)2(1), a = 8.112(2) angstrom, b = 15.507(4) angstrom, c = 16.090(5) angstrom, Z = 4, D(x) = 2.600 Mg m-3, mu(MoKalpha) 2.855 mm-1, T = 293 K, R = 0.046 for 5320 unique reflections (I > 3sigma(I)). The main structural feature is the (4-)-bridged binuclear tartrato-antimonate(III) complex [Sb2{(+)-C4H2O6}2]2-. Single crystals of the title compound of up to 4 x 4 x 6 cm3 were grown from aqueous solutions at 35-degrees-C. The electrostrictive tensor [d(ijk)] and the unclamped electro-optic tensor [r(ijk)sigma] were determined at room temperature and lambda = 633 nm. The maximum value of the electro-optic effect is two orders smaller than that of KH2PO4(KDP). The maximum electrostrictive constant is 1.3-times greater than that of alpha-quartz.

引用

页码：14 / 17

页数：4

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