CONVENIENT SYNTHESIS AND FREE-RADICAL CO-POLYMERIZATION OF P-CHLOROMETHYLSTYRENE

被引：98

作者：

KONDO, S

OHTSUKA, T

OGURA, K

TSUDA, K

机构：

[1] Nagoya Institute of Technology Gokisocho, Showa-ku

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1979年 / A13卷 / 06期

关键词：

D O I：

10.1080/00222337908056687

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

P-Chloromethylstyrene, a useful monomer for a starting material in preparation of functional polymers, is conveniently synthesized by the chloromethylation of 2-phenyl-ethyl bromide followed by dehydrobromination. This procedure is simpler and the yield is higher than those of methods previously described. Radical copolymerizations of this compound with styrene and methyl methacrylate were studied at 60C. From the copolymerization with styrene, Q and e values for p-chloromethylstyrene were calculated as Q = 1.13 and e = -0.58. Similarly, the copolymerization parameters with methyl methacrylate were obtained as Q = 1.16 and e = -0.69. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：767 / 775

页数：9

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