STEREOSPECIFIC SYNTHESIS OF 9-DEMETHYLRETINOIDS VIA PALLADIUM-CATALYZED VINYLBORONIC ACID-VINYL IODIDE CROSS COUPLING

被引：34

作者：

DELERA, AR

TORRADO, A

IGLESIAS, B

LOPEZ, S

机构：

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(00)60044-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stereospecific synthesis of 9-demethylretinoids with either trans or 11-cis geometries, based on the thallium-accelerated palladium-catalyzed cross-coupling reactions of an (E)-1-alkenylboronic acid and (E) or (Z)-alkenyl iodides, is described.

引用

页码：6205 / 6208

页数：4

共 24 条

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