Structure of cis-dichlorobis (1,10-phenanthroline) manganese(II) and cis-dichlorobis(2,2 '-bipyridine) manganese(II)

被引：3

作者：

Cechova, Danica ^{[1
]}

Martiskova, Alena ^{[1
]}

Moncol, Jan ^{[1
]}

机构：

[1] Slovak Tech Univ, Fac Chem & Food Technol, Radlinskeho 9, SK-81237 Bratislava, Slovakia

来源：

ACTA CHIMICA SLOVACA | 2014年 / 7卷 / 01期

关键词：

manganese; X-ray; crystal structure; 1,10-phenanthrolinc; 2,2 '-bipyridine;

D O I：

10.2478/acs-2014-0003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of the title compounds, [Mn(phen)(2)Cl-2] (I) and [Mn(bipy)(2)Cl-2] (II), have been determined at 150 K. The manganese atoms in both compounds are coordinated by four pyridine nitrogen atoms from two 1,10-phenanthroline or 4,4'-bipyridine ligands and two chloride anions, resulting in a distorted cis-MnN4Cl2 octahedral geometry. Both complexes are connected through C-H center dot center dot center dot Cl hydrogen bonds into frameworks. The pi-pi stacking interactions are observed in crystal structure of both ones.

引用

页码：15 / 19

页数：5

共 21 条

[11] Synthesis and catalytic activity of manganese(II) complexes of pentanedioic acid;: X-ray crystal structure of [Mn(phen)2(H2O)2][Mn(O2C(CH2)3CO2)(phen)2H2O](O2C(CH2)3CO2)•12H2O (phen = 1,10-phenanthroline) [J].

Geraghty, M ;

McCann, M ;

Casey, MT ;

Curran, M ;

Devereux, M ;

McKee, V ;

McCrea, J .

INORGANICA CHIMICA ACTA, 1998, 277 (02) :257-262

[12] A critical account on π-π stacking in metal complexes with aromatic nitrogen-containing ligands [J].

Janiak, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (21) :3885-3896

[13] Synthesis, crystal structure and catalytic activity for H2O2 disproportionation of the manganese(II) coordination polymer {[Mn(O2C(CF2)8CO2)(phen)2]H2O}n (phen=1,10-phenanthroline) [J].

Kani, Ibrahim ;

Darak, Canan ;

Sahin, Onur ;

Bueyuekguengoer, Orhan .

POLYHEDRON, 2008, 27 (04) :1238-1247

[14] Manganese-enhanced magnetic resonance imaging (MEMRI) [J].

Koretsky, AP ;

Silva, AC .

NMR IN BIOMEDICINE, 2004, 17 (08) :527-531

[15] Syntheses and X-ray crystal structures of cis-[Mn(bipy)2Cl2]•-2H2O•EtOH and cis-[Mn(phen)2Cl2] (bipy = 2,2′-bipyridine; phen = 1,10-phenanthroline); catalysts for the disproportionation of hydrogen peroxide [J].

McCann, S ;

McCann, M ;

Casey, MT ;

Jackman, M ;

Devereux, M ;

McKee, V .

INORGANICA CHIMICA ACTA, 1998, 279 (01) :24-29

[16] Structural and spectroscopic studies shed light on the mechanism of oxalate oxidase [J].

Opaleye, O ;

Rose, RS ;

Whittaker, MM ;

Woo, EJ ;

Whittaker, JW ;

Pickersgill, RW .

JOURNAL OF BIOLOGICAL CHEMISTRY, 2006, 281 (10) :6428-6433

[17] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[18] Ultrahigh (0.93 Å) resolution structure of manganese peroxidase from Phanerochaete chrysosporium: Implications for the catalytic mechanism [J].

Sundaramoorthy, Munirathinam ;

Gold, Michael H. ;

Poulos, Thomas L. .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2010, 104 (06) :683-690

[19] Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å [J].

Umena, Yasufumi ;

Kawakami, Keisuke ;

Shen, Jian-Ren ;

Kamiya, Nobuo .

NATURE, 2011, 473 (7345) :55-U65

[20] Synthesis, crystal structure and IR spectroscopy of MnII(2-IC)2(NC)(DMSO) and [MnII(2-IC)2(phen)(H2O)]•DMA;: (2-HIC, indole-2-carboxylic acid;: phen, 1,10-phenanthroline; NC, 2,9-dimethyl-1,10-phenanthroline; DMSO, dimethyl sulfoxide; DMA, dimethyl acetamide);: catalysts for the disproportionation of hydrogen peroxide [J].

Viossat, V ;

Lemoine, P ;

Dayan, E ;

Dung, NH ;

Viossat, B .

POLYHEDRON, 2003, 22 (11) :1461-1470

← 1 2 3 →