Structure of cis-dichlorobis (1,10-phenanthroline) manganese(II) and cis-dichlorobis(2,2 '-bipyridine) manganese(II)

被引：3

作者：

Cechova, Danica ^{[1
]}

Martiskova, Alena ^{[1
]}

Moncol, Jan ^{[1
]}

机构：

[1] Slovak Tech Univ, Fac Chem & Food Technol, Radlinskeho 9, SK-81237 Bratislava, Slovakia

来源：

ACTA CHIMICA SLOVACA | 2014年 / 7卷 / 01期

关键词：

manganese; X-ray; crystal structure; 1,10-phenanthrolinc; 2,2 '-bipyridine;

D O I：

10.2478/acs-2014-0003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of the title compounds, [Mn(phen)(2)Cl-2] (I) and [Mn(bipy)(2)Cl-2] (II), have been determined at 150 K. The manganese atoms in both compounds are coordinated by four pyridine nitrogen atoms from two 1,10-phenanthroline or 4,4'-bipyridine ligands and two chloride anions, resulting in a distorted cis-MnN4Cl2 octahedral geometry. Both complexes are connected through C-H center dot center dot center dot Cl hydrogen bonds into frameworks. The pi-pi stacking interactions are observed in crystal structure of both ones.

引用

页码：15 / 19

页数：5

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