Preparation of chiral phenylethanols using various vegetables grown in Algeria

被引：12

作者：

Bennamane, Manhel ^{[1
]}

Razi, Samra ^{[1
]}

Zeror, Saoussen ^{[1
]}

Aribi-Zouioueche, Louisa ^{[1
]}

机构：

[1] Badji Mokhtar Annaba Univ, Ecocompatible Asymmetr Catalysis Lab LCAE, BP 12, Annaba 23000, Algeria

来源：

BIOCATALYSIS AND AGRICULTURAL BIOTECHNOLOGY | 2018年 / 14卷

关键词：

Bioreduction; Chiral secondary alcohols; Citrus reticulata; Arbutus unedo L; Zingiber officinale;

D O I：

10.1016/j.bcab.2018.02.003

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Ginger root, strawberry tree and mandarin growing in Algeria were evaluated for their ability to stereoselective reduction of prochiral ketones. The reactivity and the enantioselectivity are strongly dependent on the biocatalyst used, and the structure of ketone. High enantioselectivities were observed for some substrates (70-99% ee) especially for the bioreduction of acetophenone 1, p-chloroacetophenone 2, tetralone 5, thiochromanone 6 and chromanone 7. Using two different batchs of Citrus reticulata from two regions of our country Annaba and Skikda, the corresponding optically active alcohols were obtained with high enantioselectivity and Skikda's variety was the best biocatalyst. The results reveal that these plants species can be a promising biocatalysts for the production of key intermediates.

引用

页码：52 / 56

页数：5

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