THE DIENE-TRANSMISSIVE [4+2]-CYCLOADDITION STRATEGY - STEREOSELECTIVE SYNTHESIS OF ADVANCED INTERMEDIATES TO QUASSINOIDS

被引：50

作者：

SPINO, C

LIU, G

TU, N

GIRARD, S

机构：

[1] Chemistry Department, University of Victoria, Victoria, BC, V8W 3P6

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 19期

关键词：

D O I：

10.1021/jo00098a017

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Complex intermediates to quassinoids', some optically active and containing many functional groups, were synthesized via a diene-transmissive Diels-Alder strategy. The stereochemistry of the key inter- and intramolecular cycloadditions was controlled by stereodefined groups on the preexisting C ring and on the tether.

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页码：5596 / 5608

页数：13

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