1,4,7,10,13-PENTAOXACYCLOPENTADECANE(15-CROWN-5) SODIUM-IODIDE COMPLEX, C10H20O5.NAI

被引：25

作者：

BUCHANAN, GW

GERZAIN, M

BENSIMON, C

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193014027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Na cation forms a 1/1 complex with 15-crown-5 ether. In this complex, Na+ is six-coordinated to the five macrocyclic O atoms (average Na-O 2.42 angstrom) and the I- ion. The coordination geometry is pentagonal pyramidal. The Na+ ion lies 0.798 (3) angstrom above the least-squares plane of the ether O atoms. All structural parameters of the crown ether are similar to those of related complexes.

引用

页码：1016 / 1019

页数：4

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