Crystal structure of bis{2-[bis(2-hydroxyethyl)amino]ethanol-(KO)-O-3, N, O'}zinc terephthalate

被引:2
|
作者
Li, Ya-Ping [1 ]
Lang, Hu [2 ]
Sun, Dajun [3 ]
Ming, Julia [4 ]
Su, Guan-Fang [1 ]
机构
[1] Second Hosp Jilin Univ, Dept Ophthalmol, 218 Zigiang St, Changchun 130041, Jilin, Peoples R China
[2] Jilin Univ Changchun, China Japan Union Hosp, Dept Orthoped, Changchun 130033, Jilin, Peoples R China
[3] Jilin Univ, China Japan Union Hosp, Dept Vasc Surg, Changchun 130033, Jilin, Peoples R China
[4] Karolinska Inst, St Eriks Eye Hosp, SE-11282 Stockholm, Sweden
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词
crystal structure; chelate; hydrogen bonding; terephthalate;
D O I
10.1107/S1600536814021771
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title salt, [Zn(C6H15NO3) (2)](C8H4O4), the Zn-II cation, located on a centre of inversion, is coordinated by four O atoms and two N atoms from two tridentate 2-[bis(2hydroxyethyl)amino]ethanol (BHEA) ligands, giving rise to a slightly distorted octahedral geometry. The terephthalate dianion, located about a centre of inversion, is not coordinated to Zn-II but is connected through O-H center dot center dot center dot O contacts with [Zn(BHEA)(2)](2+) cations, leading to a three-dimensional crystal structure.
引用
收藏
页码:M361 / +
页数:8
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