INSERTION OF DIPHENYLACETYLENE INTO THE CARBON SULFUR BOND OF PHENYLISOTHIOCYANATE AT A DIRUTHENIUM CENTER - SYNTHESIS AND X-RAY STRUCTURE OF [CP2RU2(CO)(MU-CO)()-SC(PH)=C(PH)C(=NPH))]

被引：9

作者：

HOGARTH, G

SKORDALAKIS, E

机构：

[1] Chemistry Department, University College London, London, WC1H OAJ

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 458卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80484-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heating a toluene solution of [CP2Ru2(CO)(mu-CO){mu-C(O)C(Ph)= C(Ph)}], 1, with phenylisothiocyanate affords [Cp2Ru2(CO)(mu-CO)-{mu-SC(Ph)=C(Ph)C(=NPh)}], 2, as a result of alkyne insertion into the carbon-sulfur bond of the isothiocyanate.

引用

页码：C8 / C9

页数：2

共 50 条

[31] Synthesis, X-ray structure, and protonation of [Os(C2Ph){NH-C(Ph)C6H4}(CO)(PiPr3)$ -2$/]
Esteruelas, M.A.
Lahoz, F.J.
Lopez, A.M.
Onate, E.
Oro, L.A.
Organometallics, 1995, 14 (05):
[32] ORGANIC-CHEMISTRY OF DINUCLEAR METAL CENTERS .14. SYNTHESIS, X-RAY STRUCTURE, AND REACTIVITY OF THE RUTHENIUM RUTHENIUM DOUBLE-BONDED COMPLEX [RU2(MU-CO)(MU-C2PH2)(ETA-C5H5)2]
COLBORN, RE
DYKE, AF
GRACEY, BP
KNOX, SAR
MACPHERSON, KA
MEAD, KA
ORPEN, AG
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03): : 761 - 771
[33] Synthesis and X-Ray Crystal Structure of [(thf)(4)Ca{Fe-2(CO)(6)(mu-CO)(mu-PPh2)}(2)]
Al-Shboul, Tareq Mousa Ali
Goerls, Helmar
Westerhausen, Matthias
JORDAN JOURNAL OF CHEMISTRY, 2009, 4 (02) : 111 - 118
[34] X-RAY CRYSTAL-STRUCTURE AND MOLECULAR-DYNAMICS OF THE MU-DIMETHYLCARBENE COMPLEX [RU2(CO)2(MU-CO)(MU-CME2)(ETA-C5H5)2]
DYKE, AF
KNOX, SAR
MEAD, KA
WOODWARD, P
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (16) : 861 - 862
[35] REVERSIBLE CYCLIZATION REACTIONS TO FORM RUTHENAFURANS - X-RAY CRYSTAL-STRUCTURE OF [RU(CO)(C(PH)OC(OET)=CH)CL(PME(2)PH)(2)]
WAUGH, MP
MORRAN, PD
MAWBY, RJ
KORBER, FCF
REID, AJ
REYNOLDS, CD
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (09) : 941 - 942
[36] FORMAL INSERTION OF CARBON INTO A C=C DOUBLE-BOND ON AN RU5 CLUSTER - X-RAY STRUCTURE OF RU5(MU-4-CC11H12)-(MU-3-SME)2(MU-PPH2)2(CO)9
ADAMS, CJ
BRUCE, MI
SKELTON, BW
WHITE, AH
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 444 (1-2) : C44 - C46
[37] Synthesis, nucleophilic attack on, and rearrangement of cationic ruthenafurans: X-ray crystal structures of [Ru(CO)(2){C(Ph)NHCMe(3)}(CH(2)CO(2)Et)(PMe(2)Ph)(2)][PF6] and [Ru(CO)(2){C(Me)=CHC(O)OEt}(PMe(2)Ph)(2)][PF6]
Morran, PD
Mawby, RJ
Wilson, GD
Moore, MH
CHEMICAL COMMUNICATIONS, 1996, (02) : 261 - 262
[38] Photochemically promoted regiospecific P-C bond cleavage in the diruthenium compound Ru2(CO)2(bmf):: X-ray diffraction structure of Ru2(CO)6 [μ-C=C(PPh2)C(O)OCH(OMe)](μ-PPh2)
Botty, Simon G.
Shen, Huafeng
Richmond, Michael G.
JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (13) : 1457 - 1467
[39] SYNTHESIS AND CRYSTAL-STRUCTURE OF PDMO (MU-PH(2)PPY)(2)(MU-CO) (CO)(2)I-2-CENTER-DOT-0.5CH2CL2
ZHANG, ZZ
XI, HP
WANG, HG
WANG, RJ
ACTA CHIMICA SINICA, 1993, 51 (11) : 1053 - 1058
[40] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE HETEROMETALLIC PLATINUM MERCURY CLUSTER [(PT-4(MU-CO)(4)(PME(2)PH)(4))(MU(3)-HGI)(2)]
DAHMEN, KH
IMHOF, D
VENANZI, LM
GERFIN, T
GRAMLICH, V
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 486 (1-2) : 37 - 43

← 1 2 3 4 5 →