INSERTION OF DIPHENYLACETYLENE INTO THE CARBON SULFUR BOND OF PHENYLISOTHIOCYANATE AT A DIRUTHENIUM CENTER - SYNTHESIS AND X-RAY STRUCTURE OF [CP2RU2(CO)(MU-CO)()-SC(PH)=C(PH)C(=NPH))]

被引：9

作者：

HOGARTH, G

SKORDALAKIS, E

机构：

[1] Chemistry Department, University College London, London, WC1H OAJ

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 458卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80484-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heating a toluene solution of [CP2Ru2(CO)(mu-CO){mu-C(O)C(Ph)= C(Ph)}], 1, with phenylisothiocyanate affords [Cp2Ru2(CO)(mu-CO)-{mu-SC(Ph)=C(Ph)C(=NPh)}], 2, as a result of alkyne insertion into the carbon-sulfur bond of the isothiocyanate.

引用

页码：C8 / C9

页数：2

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