EXPERIMENTAL-STUDY ON FLAMMABILITY LIMIT OF A CHLORINE TRIFLUORIDE DICHLOROSILANE NITROGEN MIXTURE

被引:6
作者
LEE, SG [1 ]
OHTANI, H [1 ]
UEHARA, Y [1 ]
ARAMAKI, M [1 ]
机构
[1] CENT GLASS CO LTD,CHIYODA KU,TOKYO 101,JAPAN
关键词
CHLORINE TRIFLUORIDE; DICHLOROSILANE; FLAMMABILITY LIMIT;
D O I
10.1016/0950-4230(92)80023-2
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The flammability limit of a chlorine trifluoride (ClF3)/dichlorosilane (SiH2Cl2)/nitrogen (N2) mixture was investigated experimentally. In this study, a SiH2Cl2/N2 mixture was first introduced into an explosion vessel and a ClF3/N2 mixture was then injected into the vessel. Spontaneous ignition was observed during the injection when the final ClF3/SiH2Cl2/N2 mixture was in a flammable range. Various compositions were tested to determine the flammability diagram of a ClF3/SiH2Cl2/N2 mixture. From the flammability diagram, the lower flammability limits for spontaneous ignition were found to be 0.3 vol% for both ClF3 and SiH2Cl2. Below this limit ignition did not occur even when an electronic spark was applied.
引用
收藏
页码:192 / 195
页数:4
相关论文
共 5 条
[1]   FLAMMABILITY LIMITS OF ARSINE AND PHOSPHINE [J].
OHTANI, H ;
HORIGUCHI, S ;
URANO, Y ;
IWASAKA, M ;
TOKUHASHI, K ;
KONDO, S .
COMBUSTION AND FLAME, 1989, 76 (3-4) :307-310
[2]  
OHTANI H, 1988, J JPN SOC SAFETY ENG, V27, P4
[3]   PREMIXED SILANE-OXYGEN-NITROGEN FLAMES [J].
TOKUHASHI, K ;
HORIGUCHI, S ;
URANO, Y ;
IWASAKA, M ;
OHTANI, H ;
KONDO, S .
COMBUSTION AND FLAME, 1990, 82 (01) :40-50
[4]  
YOKOKAWA H, 1988, J NATL CHEM LAB IND, V83
[5]  
1990, HDB SPECIALTY GAS SA