SOLVENT EFFECTS IN THE FLUORINATION OF AROMATIC-MOLECULES WITH F-TEDA-BF4

被引：36

作者：

ZUPAN, M ^{[1
]}

ISKRA, J ^{[1
]}

STAVBER, S ^{[1
]}

机构：

[1] UNIV LJUBLJANA,JOZEF STEFAN INST,LJUBLJANA,SLOVENIA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 70卷 / 01期

关键词：

SOLVENT EFFECTS; FLUORINATION; AROMATE MOLECULES; F-TEDA-BF4; STRUCTURAL EFFECTS; ADDITION PROCESSES;

D O I：

10.1016/0022-1139(94)03146-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The type of functionalization of an aromatic molecule achieved with 1-chloromethyl-4-fluoro-1,4-diazobicyclo-(2,2,2)octane bis-tetrafluoroborate, 'F-TEDA-BF4', in trifluoroacetic acid depends on its structure: naphthalene and phenanthrene gave fluorinated products, anthracene gave the trifluoroacetate, while an addition process occurred with 9-methoxy-phenanthrene in methanol, and an addition-elimination process in trifluoroacetic acid.

引用

页码：7 / 8

页数：2

共 16 条

[1]

Banks R.E., 1992, US Patent, Patent No. [5086178, 5,086,178]

[2] 1-ALKYL-4-FLUORO-1,4-DIAZONIABICYCLO[2.2.2]OCTANE SALTS - A NOVEL FAMILY OF ELECTROPHILIC FLUORINATING AGENTS [J].