EXCESS MOLAR VOLUMES OF (1-CHLOROPENTANE OR 1-CHLOROHEXANE PLUS HEPTANE PLUS DECANE) AT THE TEMPERATURE 298.15-K

被引：9
|
作者：
LORENZANA, MT [1 ]
JIMENEZ, E [1 ]
LEGIDO, JL [1 ]
FERNANDEZ, J [1 ]
ANDRADE, MIP [1 ]
机构：
[1] UNIV SANTIAGO,DEPT FIS APL,CAMPUS UNIV,E-15706 SANTIAGO,SPAIN
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 1993年 / 25卷 / 09期
关键词：
D O I：
10.1006/jcht.1993.1100
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Excess molar volumes VEm at T = 298.15 K of (1-chloropentane + heptane + decane) and (1-chlorohexane + heptane + decane) were determined using a DMA 60/602 Anton-Paar densimeter. The sign of VEm varied with the composition for both mixtures. The experimental values were compared with the results obtained with some empirical methods for the estimation of ternary properties from binary results and with the Nitta et al. group-contribution model. For these ternary mixtures the same behaviour that had been observed in (1-chloroalkane + an n -alkane) was found: excess volumes decrease with the 1-chloroalkane length. © 1993 Academic Press Ltd.
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页码：1041 / 1047
页数：7
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